Van der Waals's equation of state is obeyed by real gases. For $n$ moles of a real gas,the expression will be :-

The relation between pressure exerted by an ideal gas $(P_{ideal})$ and observed pressure $(P_{real})$ is given by the equation
$P_{ideal} = P_{real} + \frac{an^2}{V^2}$
$(i)$ If pressure is taken in $N \ m^{-2}$,number of moles in $mol$,and volume in $m^3$,calculate the unit of $a$.
$(ii)$ What will be the unit of $a$ when pressure is in atmosphere and volume in $dm^3$?

In the van der Waals equation of state for a real gas,the term representing intermolecular forces is .......

Which intermolecular force is most responsible for the liquefaction of inert gases?

In the following compressibility factor $(Z)$ versus pressure graph at $300 \, K$,the compressibility of $CH_{4}$ at pressure $< 200 \, bar$ deviates from ideal behaviour because

Four gases $P, Q, R$ and $S$ have almost same values of $b$ but their $a$ values ($a, b$ are van der Waals' constants) are in the order $Q < R < S < P$. At a particular temperature among the four gases, the most liquefiable one is